Statistics 10th Edition Witte Pdf 18 _BEST_
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Statistics 10th Edition Witte Pdf 18
Statistics Witte 10th Edition PDF – WittePDF.com
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Enantioselective 1,2-Addition of Aryl Boronic Acids to Enolizable α,β-Unsaturated γ-Substituted Alkenes Mediated by Indium Catalysts: An EPR Spectroscopic Approach.
A chiral indium-based catalyst 2,3-bis(indium)-N-tosyl-1,2-bis(diisopropylphosphinomethyl)-1,2-dihydronaphthalene-1-carbene (L3/N-Ts-BINAP) was prepared and its catalytic application was demonstrated in the enantioselective 1,2-addition of aryl boronic acids to (Z)-5-phenyldivinyl-4-phenylpent-4-en-2-one (1), which is enantiomerically enriched and derived from 2,3-dimethylbutanal. An EPR approach was applied to probe the reaction mechanism, and the results indicated that the reaction occurs in a bifurcating manner. The two-step reaction includes a step-wise addition, the first involving the boronic acid coordination to the tosyl group followed by the attack of the carbanion on the olefin, and the second an addition of the formed carbanion to the olefin (or an indium intermediate). The X-ray crystal structure of the (
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